CATALYTIC ACTIVITY: Acyl-CoA + acetate = a fatty acid anion + acetyl-CoA.PATHWAY: Lipid metabolism; short-chain fatty acid metabolism.
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Based on sequence similarity, AtoD is predicted to be an acetate CoA-transferase . [More information is available at EcoCyc: EG11669].
Based on sequence similarity, AtoA is predicted to be an acetate CoA-transferase . [More information is available at EcoCyc: EG11670].
CoA transferase having broad substrate specificity for short-chain acyl-CoA thioesters with the activity decreasing when the length of the carboxylic acid chain exceeds four carbons. Exhibits high activity with acetoacetyl-CoA, propionyl-CoA, crotonoyl-CoA or butyryl-CoA as donors, with acetate as an acceptor. When acetyl-CoA is used as the donor, propionate, acetoacetate, butyrate, isobutyrate, and 4-hydroxybutyrate can be utilized as acceptors but not isovalerate. May play a role in short-chain fatty acid metabolism in E.coli.
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